量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系     

许旋  罗一帆  李华祥 《广东海洋大学学报》1992,(2)

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。  相似文献   

流动VLBI站氢原子钟的研制与性能测试     

张为群  林传富  于双林  张一平  王关忠  张健  杨佩红 《天文学报》2001,42(1):94-100

氢脉泽是射电天文所必需的频率标准.文中对为流动vLBI站研制的新一代氢脉泽的物理结构特点进行了讨论，包括对腔泡结构、磁屏蔽、原子束光学系统等.同时性能测试表明在80秒到1天之间频率稳定度优于1×10  相似文献   

Determination of physical parameters of NGC 2023 using the hyperfine NH₃ spectrum     

Xing Jun  Xu Lan-Ping 《Chinese Astronomy and Astrophysics》1985,9(4):283-290

An improved approach is given for deriving the physical parameters of a molecular cloud by its NH₃ rotation-inversion hyperfine spectra. The optical depth τ₀(1, 1) of NH₃ (1,1) is obtained by considering the blending effect of the magnetic hyperfine spectral lines, the (1-1) excitation temperature T_ex (1, 1) is calculated by a two level model, the effect of different collision rate and the thermalization of the (1, 1) inversion lines are discussed, the rotation temperature T_R ( 2, 1) between the NH₃ levels (2, 2) and (1, 1) and the column density N( 1, 1) of the NH₃ (1, 1) inversion level are derived, the results of the total column density from different assumptions for the abundance ratio of ortho-NH₃ and para-NH₃ are also discussed.

This approach is used for the molecular cloud NGC 2023 by using the relevant observed data and its optical depth and other physical parameters are obtained.  相似文献   

The Kaidun meteorite: Mineralogy of an unusual CM1 lithology     

Michael E. ZOLENSKY  Andrei V. IVANOV  S. Vincent YANG  David W. MITTLEFEHLDT  Kazumasa OHSUMI 《Meteoritics & planetary science》1996,31(4):484-493

Abstract Kaidun is a breccia of disparate enstatite and carbonaceous chondrite clasts that continues to provide real surprises. Many Kaidun clasts have been intensely altered by aqueous fluids, as evidenced by the widespread occurrence of ferromagnesian phyllosilicates and by the presence of carbonate- and phyllo-silicate-filled veins. In this report, we describe an unusual CM lithology containing many mineralogical features not previously reported from any meteorite, including pyrrhotite, with exclusive needlelike morphologies and thick mantles of phyllosilicate, and complex aggregates of phyllosilicate, melanite garnet, crosscut by pentlandite veins. The latter features appear to be due in large part to extensive hydrothermal alteration at temperatures on the order of 450 °C, which is significantly higher than that attained during secondary processing from other known CM material.  相似文献   

八庙—青山金红石矿床化学成分与成矿关系     

徐少康  李博昀  程建祖  刘振山 《河南国土资源》1996,(4)

本矿床是我国金红石矿床重要的成因及工业类型，为具有特定化学成分的岩石在特定变质条件下形成的。本文通过对大量数据的处理，查明了化学成分与成矿的关系：高Ａｌ２Ｏ３、ＭｇＯ、Ｆｅ２Ｏ３＋ＦｅＯ、Ｋ２Ｏ、Ｐ２Ｏ５、Ｈ２Ｏ＋、ＭｎＯ，低ＳｉＯ２、ＣａＯ、Ｎａ２Ｏ、ＣＯ２、Ｓ等，利于钛富集；高ＴｉＯ２、ＭｇＯ、Ｐ２Ｏ５、Ｓ，低ＳｉＯ２、ＣａＯ、Ｋ２Ｏ、Ａｌ２Ｏ３、Ｆｅ２Ｏ３／ＦｅＯ，利于金红石形成；高Ｓｃ、Ｚｒ、Ｎｉ、Ｚｎ及Ｌａ／Ｙｂ，低Ｙ、Ｎｂ、Ｔｈ、Ｃｄ、Ｂａ、Ｂｅ、ΣＲＥＥ，利于金红石纯度提高。对研究矿床成因及寻找新的同类矿床等有重要意义  相似文献   

Ion-cyclotron instability and electron acceleration in coronal loops     

Dingyi Li  Deyu Wand  Shihtung Tsai  Minjian Xu  Dingyi Mao 《Solar physics》1993,143(2):235-245

Quasi-electrostatic electron and ion-cyclotron instabilities are studied. The result indicates that the higher harmonic ion cyclotron instabilities (ICI) can be excited while the fast ions produced from reconnection are injected into a coronal loop. Part of the energetic ions can be dragged out of the magnetic mirror turning points and a negative plasma potential is generated. The plasma potential may directly accelerate the electrons up to the relativistic velocity within a short time. This acceleration is similar to the processes occurring in the magnetic mirror devices of controlled thermonuclear fusion. The spectrum and flux of accelerated electrons have also been obtained. Some observational results during the solar flare might be explained by this acceleration mechanism.  相似文献   

黑洞吸积盘的演化及温度分布的热不稳定性     

汪定雄  杨兰田  陆烨 《中国天文和天体物理学报》1994,(4)

本文在Ｔｈｏｒｎｅ工作的基础上讨论了吸积盘中黑洞的有关参量的演化，以及由Ｓｃｈｗａｒｚｓｃｈｉｌｄ黑洞吸积盘向Ｋｅｒｒ黑洞吸积盘演化过程中对吸积盘辐射通量的影响，最后针对几个典型的辐射过程，分别讨论了黑洞吸积盘在牛顿框架中的温度分布方程与广义相对论的温度分布方程的热不稳定性，并给出此类问题的热不稳定性的判据。  相似文献   

河外H_2O超脉泽辐射     

徐烨  蒋栋荣  郑兴武  俞志尧 《天文学进展》2001,(3)

介绍了近年来河外Ｈ２Ｏ超脉泽的主要观测结果。Ｈ２Ｏ超脉泽通常起源于活动星系核中央的拱核盘。它们主要寄生在 Ｓｅｒｆｅｒｔ ２星系或低电离核区。至今为止，已有２０个星系探测到Ｈ２Ｏ超脉泽。脉泽辐射的各向同性光度为１０～６０００Ｌ⊙。所有超脉泽星系显示出核的活动，显然，脉泽是由核活动所产生的射电和Ｘ射线光子或激波来抽运的。Ｈ２Ｏ超脉泽倾向存在于高倾斜度的星系，这使得沿视线上的分子柱密度增高，产生足够大的放大光深。最有可能产生Ｈ２Ｏ超脉泽辐射的星系应有一个包含着射电源的侧向的分子盘以及一个适当的抽运机制。  相似文献   

DCMT光电扫描主测微器的设计与研究     

李志刚  李焕信  方福胜  朱紫  许林生 《时间频率学报》1993,(1)

DCMT主测微器不同于其它类型的子午环测微器,它具有自校准测定仪器参数的功能。该测微器采用了活动光栅的方案,其优点是能观测近极星和各类准直像;活动光栅另一个显著优点是不同赤纬星几乎可用相同的观测时间.对“V”形光栅的工作原理和误差进行了详细讨论,并给出了一组严格的公式。其系统误差来源有:光栅形状改正、光栅驱动方向相对于光栅的倾斜、光栅驱动方向相对于赤径方向的倾斜、星径曲率改正。  相似文献   

Exposure dating and reinterpretation of coarse debris accumulations (‘rock glaciers’) in the Cairngorm Mountains,Scotland     

Colin K. Ballantyne  Christoph Schnabel  Sheng Xu 《第四纪科学杂志》2009,24(1):19-31

Relict rock glaciers have considerable potential for contributing to palaeoclimatic reconstruction, but this potential is often undermined by lack of dating control and problems of interpretation. Here we reinvestigate and date four proposed ‘rock glaciers’ in the Cairngorm Mountains and show that the morphology of only one of these appears consistent with that of a true rock glacier produced by creep of underlying ice or ice‐rich sediment. All four features comprise rockslide or rock avalanche runout debris, and the possibility that all four represent unmodified runout accumulations cannot be discounted. Surface exposure dating of the four debris accumulations using cosmogenic ¹⁰Be produced uncertainty‐weighted mean ages of 15.4 ± 0.8 ka, 16.2 ± 1.0 ka, 12.1 ± 0.6 ka and 12.7 ± 0.8 ka. All four ages imply emplacement under cold stadial conditions, two prior to the Windermere Interstade of ca. 14.5–12.9 cal. ka BP and two during the Loch Lomond Stade of ca. 12.9–11.5 cal. ka BP. The above ages indicate that paraglacial rock‐slope failure on granite rockwalls occurred within a few millennia after deglaciation. The mean exposure ages obtained for runout debris at two sites – Strath Nethy (16.2 ± 1.0 ka) and Lairig Ghru (15.4 ± 0.8 ka) – are consistent with basal radiocarbon ages from Loch Etteridge, 22 km to the southwest (mean = 15.6 ± 0.3 cal. ka BP) and imply widespread deglaciation of the Cairngorms and adjacent valleys before 15 ka and possibly 16 ka. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献